Chemistry of Organo-hybrids

This book provides readers with a one-stop entry into the chemistry of varied hybrids and applications, from a molecular synthetic standpoint • Describes introduction and effect of organic structures on specific support components (carbon-based materials, proteins, metals, and polymers). • Chapters cover hot topics including nanodiamonds, nanocrystals, metal-organic frameworks, peptide bioconjugates, and chemoselective protein modification • Describes analytical techniques, with pros and cons, to validate synthetic strategies • Edited by internationally-recognized chemists from different backgrounds (synthetic polymer chemistry, inorganic surfaces and particles, and synthetic organic chemistry) to pull together diverse perspectives and approaches

Preface vii Contributors ix 1 COVALENT ORGANIC FUNCTIONALIZATION AND CHARACTERIZATION OF CARBON NANOTUBES 1 Cécilia Ménard-Moyon 2 FUNCTIONALIZED GRAPHENES 36 Iban Azcarate, David Lachkar, Emmanuel Lacôte, Jennifer Lesage de la Haye, and Anne-Laure Vallet 3 NANODIAMONDS: EMERGENCE OF FUNCTIONALIZED DIAMONDOIDS AND THEIR UNIQUE APPLICATIONS 69 Maria A. Gunawan, Paul Kahl, Didier Poinsot, Bruno Domenichini, Peter R. Schreiner, Andrey A. Fokin, and Jean-Cyrille Hierso 4 TITANIA-BASED HYBRID MATERIALS: FROM MOLECULAR PRECURSORS TO THE CONTROLLED DESIGN OF HIERARCHICAL HYBRID MATERIALS 114 Laurence Rozes, Loïc D’Arras, Chloé Hoffman, François Potier, Niki Halttunen, and Lionel Nicole 5 FUNCTIONALIZATION OF ZIRCONIUM OXIDE SURFACES 168 Marc Petit and Julien Monot 6 FUNCTIONAL METAL–ORGANIC FRAMEWORKS: SYNTHESIS AND REACTIVITY 200 Flavien L. Morel, Xiaoying Xu, Marco Ranocchiari, and Jeroen A. van Bokhoven 7 SURFACE CHEMISTRY OF COLLOIDAL SEMICONDUCTOR NANOCRYSTALS: ORGANIC, INORGANIC, AND HYBRID 233 Richard Brutchey, Zeger Hens, and Maksym V. Kovalenko 8 COVALENT ORGANIC FUNCTIONALIZATION OF NUCLEIC ACIDS 272 Michel Arthur and Mélanie Etheve-Quelquejeu 9 CHEMOSELECTIVE PROTEIN MODIFICATIONS: METHODS AND APPLICATIONS FOR THE FUNCTIONALIZATION OF VIRAL CAPSIDS 299 Divya Agrawal and Christian P. R. Hackenberger 10 CYCLODEXTRINS–METAL HYBRIDS 349 Maxime Guitet, Mickaël Ménand, and Matthieu Sollogoub 11 POST-FUNCTIONALIZATION OF POLYMERS VIA ORTHOGONAL LIGATION CHEMISTRY 395 Anja S. Goldmann, M. Glassner, Andrew J. Inglis, and Christopher Barner-Kowollik 12 POLYMER–PROTEIN/PEPTIDE BIOCONJUGATES 466 Paul Wilson, Julien Nicolas, and David M. Haddleton 13 HYBRID MATERIALS BUILT FROM (PHOSPHORUS) DENDRIMERS 503 Anne-Marie Caminade, Beatrice Delavaux-Nicot, and Jean-Pierre Majoral Index