Ceramics for Environmental and Energy Applications II

A collection of papers from the below symposia held during the 10th Pacific Rim Conference on Ceramic and Glass Technology (PacRim10), June 2-7, 2013, in Coronado, California 2012: Solid Oxide Fuel Cells and Hydrogen Technology Direct Thermal to Electrical Energy Conversion Materials and Applications Photovoltaic Materials and Technologies Ceramics for Next Generation Nuclear Energy Advances in Photocatalytic Materials for Energy and Environmental Applications Ceramics Enabling Environmental Protection: Clean Air and Water Advanced Materials and Technologies for Electrochemical Energy Storage Systems Glasses and Ceramics for Nuclear and Hazardous Waste Treatment

Preface ix Recent Research Activities for Future Challenges in Global Energy and Environment in Toyota Central R&D Labs., Inc. (TCRDL) 1 Tomoyoshi Motohiro SOLID OXIDE FUEL CELLS AND HYDROGEN TECHNOLOGY Structural and Electrical Characterization of PrxCe0.95-xGd0.05O2.s (0.15 less than/equal to x less than/equal to 0.40) as Cathode Materials for Low Temperature SOFC 13 Rajalekshmi Chockalingam, Suddhasatwa Basu, and Ashok Kumar Ganguli Solid Oxide Metal-Air Batteries for Advanced Energy Storage 25 Xuan Zhao, Yunhui Gong, Xue Li, Nansheng Xu, and Kevin Huang Fabrication of Ce02/Al Multilayer Thin Films and the Thermal Behavior 33 Shumpei Kurokawa, Takashi Hashizume, Masateru Nose, and Atsushi Saiki DIRECT THERMAL TO ELECTRICAL ENERGY CONVERSION MATERIALS AND APPLICATIONS Reduced Strontium Titanate Thermoelectric Materials 45 Lisa A. Moore and Charlene M. Smith PHOTOVOLTAIC MATERIALS AND TECHNOLOGIES Densification and Properties of Fluorine Doped Tin Oxide (FTO) Ceramics by Spark Plasma Sintering 59 Meijuan Li, Kun Xiang, Qiang Shen, and Lianmeng Zhang Interfacial Character and Electronic Passivation in Amorphous Thin-Film Alumina for Si Photovoltaics 65 L.R. Hubbard, J.B. Kana-Kana, and B.G. Potter, Jr. CERAMICS FOR NEXT GENERATION NUCLEAR ENERGY SiC/SiC Fuel Cladding by NITE Process for Innovative LWR Pre-Composite Ribbon Design and Fabrication 79 Yuuki Asakura, Daisuke Hayasaka, Joon-Soo Park, Hirotatsu Kishimoto, and Akira Kohyama SiC/SiC Fuel Cladding by NITE Process for Innovative Light Water Reactor - Compatibility with High Temperature Pressurized Water 85 C. Kanda, Y. Kanda, H. Kishimoto, and A. Kohyama SiC/SiC Fuel Cladding by NITE Process for Innovative LWR-Concept and Process Development of Fuel Pin Assembly Technologies 93 Hirotatsu Kishimoto, Tamaki Shibayama, Yuuki Asakura, Daisuke Hayasaka, Yutaka Kohno, and Akira Kohyama "INSPIRE" Project for R&D of SiC/SiC Fuel Cladding by NITE Method 99 Akira Kohyama SiC/SiC Fuel Cladding by NITE Process for Innovative LWR-Cladding Forming Process Development 109 Naofumi Nakazato, Hirotatsu Kishimoto, Yutaka Kohno, and Akira Kohyama ADVANCES IN PHOTOCATALYTIC MATERIALS FOR ENERGY AND ENVIRONMENTAL APPLICATIONS Preparation of Brookite-Type Titanium Oxide Nanocrystal by Hydrothermal Synthesis 119 S. Kitahara, T. Hashizume, and A. Saiki Effect of Atmosphere on Crystallisation Kinetics and Phase Relations in Electrospun Ti02 Nanofibres 125 H. Albetran, H. Haroosh, Y. Dong, B. H. O'Connor, and I. M. Low Electronic and Optical Properties of Nitrogen-Doped Layered Manganese Oxides 135 Giacomo Giorgi and Koichi Yamashita CERAMICS ENABLING ENVIRONMENTAL PROTECTION: CLEAN AIR AND WATER Understanding the Effect of Dynamic Feed Conditions on Water Recovery from IC Engine Exhaust by Capillary Condensation with Inorganic Membranes 143 Melanie Moses DeBusk, Brian Bischoff, James Hunter, James Klett, Eric Nafziger, and Stuart Daw Reliability of Ceramic Membranes of BSCF for Oxygen Separation in a Pilot Membrane Reactor 153 E. M. Pfaff, M. Oezel, A. Eser, and A. Bezold ADVANCED MATERIALS AND TECHNOLOGIES FOR ELECTROCHEMICAL ENERGY STORAGE SYSTEMS In Situ Experimentation with Batteries using Neutron and Synchrotron X-Ray Diffraction 167 Neeraj Sharma Electrochemical Performance of LiNi1/3Co1/3Mn1/302 Lithium Polymer Battery Based on PVDF-HFP/m-SBA15 Composite Polymer Membranes 181 Chun-Chen Yang and Zuo-Yu Lian GLASSES AND CERAMICS FOR NUCLEAR AND HAZARDOUS WASTE TREATMENT Borosilicate Glass Foams from Glass Packaging Residues 205 R. K.Chinnam, Silvia Molinaro, Enrico Bernardo, and Aldo R. Boccaccini The Durability of Simulated UK High Level Waste Glass Compositions Based on Recent Vitrification Campaigns 211 Mike T. Harrison and Carl J. Steele Scaled Melter Testing of Noble Metals Behavior with Japanese HLW Streams 225 Keith S. Matlack, Hao Gan, Ian L. Pegg, Innocent Joseph, Bradley W. Bowan, Yoshiyuki Miura, Norio Kanehira, Eiji Ochi, Tamotsu Ebisawa, Atsushi Yamazaki, Toshiro Oniki, and Yoshihiro Endo Suppression of Yellow Phase Formation during Japanese HLW Vitrification 237 Hao Gan, Keith S. Matlack, Ian L. Pegg, Innocent Joseph, Bradley W. Bowan, Yoshiyuki Miura, Norio Kanehira, Eiji Ochi, Toshiro Oniki, and Yoshihiro Endo Cold Crucible Vitrification of Hanford HLW Surrogates in Aluminum-Iron-Phosphate Glass 251 S. V. Stefanovsky, S. Y. Shvetsov, V. V. Gorbunov, A. V. Lekontsev, A. V. Efimov, I. A. Knyazev, O. I. Stefanovsky, M. S. Zen'kovskaya, and J. A. Roach Hafnium and Samarium Speciation in Vitrified Radioactive Incinerator Slag 265 G. A. Malinina, S. V. Stefanovsky, A. A. Shiryaev, and Y. V. Zubavichus Author Index 273