Electrochemical Methods: Fundamentals and Applications (3版)

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The latest edition of a classic textbook in electrochemistry The third edition of Electrochemical Methods has been extensively revised to reflect the evolution of electrochemistry over the past two decades, highlighting significant developments in the understanding of electrochemical phenomena and emerging experimental tools, while extending the book's value as a general introduction to electrochemical methods. This authoritative resource for new students and practitioners provides must-have information crucial to a successful career in research. The authors focus on methods that are extensively practiced and on phenomenological questions of current concern. This latest edition of Electrochemical Methods contains numerous problems and chemical examples, with illustrations that serve to illuminate the concepts contained within in a way that will assist both student and mid-career practitioner. Significant updates and new content in this third edition include: An extensively revised introductory chapter on electrode processes, designed for new readers coming into electrochemistry from diverse backgrounds New chapters on steady-state voltammetry at ultramicroelectrodes, inner-sphere electrode reactions and electrocatalysis, and single-particle electrochemistry Extensive treatment of Marcus kinetics as applied to electrode reactions, a more detailed introduction to migration, and expanded coverage of electrochemical impedance spectroscopy The inclusion of Lab Notes in many chapters to help newcomers with the transition from concept to practice in the laboratory The new edition has been revised to address a broader audience of scientists and engineers, designed to be accessible to readers with a basic foundation in university chemistry, physics and mathematics. It is a self-contained volume, developing all key ideas from the fundamental principles of chemistry and physics. Perfect for senior undergraduate and graduate students taking courses in electrochemistry, physical and analytical chemistry, this is also an indispensable resource for researchers and practitioners working in fields including electrochemistry and electrochemical engineering, energy storage and conversion, analytical chemistry and sensors.

Natural Protein-Based Strategies for Electrochemical Energy Storage (1版)

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【簡介】 Electrochemical energy storage (EES) is increasingly critical for development and applications of numerous technologies or new products, such as portable electronics, electric vehicles, and large-scale energy storage systems. The expanding market of EES requires products that are low cost, environmentally friendly, and with high energy density. Natural proteins are abundant bio-macromolecules and possess numerous useful functional groups through millions of years of evolution. By the rational control of the protein molecular architectures, we can effectively develop important component materials with functionalities for energy storage systems via appropriately utilizing the functional groups of proteins. Therefore, tremendous research efforts on application of natural proteins for enhancing the performance of EES have been reported. In this book, advanced strategies for adopting various natural proteins to development of the components of EES are comprehensively summarized, such as protein-derived active materials, separators, binders, electrolytes, and more. The advantages and challenges of the various strategies are discussed in detail. Finally, future perspectives of the protein-based strategies toward high-performance EES are proposed.

Electrochemical Impedance Spectroscopy and Related Techniques

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【簡介】 This book begins by introducing the basic concepts of impedance to non-specialist readers, who may have only an elementary knowledge of physics and mathematics. Mathematical concepts are explained clearly at appropriate points in a series of Theory Notes. Subsequent chapters cover RCL (resistor, capacitor, inductor) circuits before developing the key ideas behind the application of impedance spectroscopy to electrochemical systems. Circuit elements used to model electron transfer, double-layer charging and diffusion are described in detail, along with Kramers–Kronig testing of experimental data. The book explains how potentiostats and frequency-response analyzers work and evaluates a wealth of experimental data obtained either during the annual Bath impedance courses or in the laboratories of the author and his colleagues. Topics covered include not only conventional electrochemical systems, such as the rotating disc electrode and ultramicroelectrodes, but also unconventional solar cells and the application of frequency-resolved techniques in spectroelectrochemistry. Finally, the last two chapters introduce techniques based on modulation of light intensity rather than voltage or current. The book concludes with worked answers to the problems set out in earlier chapters. 【目錄】 Getting Started Frequency-Response Analysis Putting the E in EIS: Frequency-Response Analysis of Electrochemical Systems Kramers–Kronig Testing of Impedance Data and Inductive Loops The Potentiostat and the Frequency-Response Analyzer: How Do They Work? Examples of Finite Diffusion Impedance: The Rotating Disc Electrode and the Ultramicroelectrode Photoelectrochemical Impedance Spectroscopy of Dye-Sensitized Solar Cells and Metal Halide Perovskite Cells Electrochromic Systems: Potential-Modulated Absorbance Spectroscopy of Polyaniline, and Light-Modulated Absorbance of Haematite Intensity-Modulated Techniques: Application of IMPS and IMVS to Characterize Unconventional Solar Cells Applications of IMPS and PEIS to Study Photoelectrode Kinetics